翻訳と辞書 Words near each other ・ Wilkinson Lake ・ Wilkinson matrix ・ Wilkinson Memorial Trail ・ Wilkinson Microwave Anisotropy Probe ・ Wilkinson Peaks ・ Wilkinson power divider ・ Wilkinson River ・ Wilkinson Street tram stop ・ Wilkinson Sword ・ Wilkinson TMC ・ Wilkinson Township, Cass County, Minnesota ・ Wilkinson v ASB Bank Ltd ・ Wilkinson v Downton ・ Wilkinson v. Austin ・ Wilkinson v. United States ・ Wilkinson's catalyst ・ Wilkinson's polynomial ・ Wilkinson, Illinois ・ Wilkinson, Indiana ・ Wilkinson, Mississippi ・ Wilkinson, West Virginia ・ Wilkinson, Wisconsin ・ Wilkinson-Boineau House ・ Wilkinson-Dozier House ・ Wilkinson-Martin House ・ Wilkinsonellus ・ Wilkinsons ・ Wilknicki Młyn ・ Wilkniss Mountains ・ Wilknity Dictionary Lists mini英和辞書 mini和英辞書 Webster 1913 Latin-English FOLDOC Wikipedia English ウィキペディア

翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Wilkinson's catalyst ： ウィキペディア英語版 Wilkinson's catalyst |Section8= }} Wilkinson's catalyst is the common name for chlorotris(triphenylphosphine)rhodium(I), a coordination compound with the formula RhCl(PPh3)3 (Ph = phenyl). It is named after the chemist and Nobel Laureate, Sir Geoffrey Wilkinson who popularized its use. ==Structure and basic properties== The compound is a square planar, 16-electron complex. It is usually obtained in the form of a red-violet crystalline solid from the reaction of rhodium(III) chloride with excess triphenylphosphine.〔Bennett, M. A.; Longstaff, P. A. Complexes of Rhodium(I) with Triphenylphosphine. ''Chem. Ind. (London)'' 1965, p. 846.〕 The synthesis is conducted in refluxing ethanol which helps with the reduction.〔"Tris(triphenylphosphine)halorhodium(I)" J. A. Osborn, G. Wilkinson, Inorganic Syntheses, 1967, Volume 10, p. 67. 〕 Triphenylphosphine serves as the reducing agent yielding triphenylphosphine oxide. :RhCl3(H2O)3 + 4 PPh3 → RhCl(PPh3)3 + OPPh3 + 2 HCl + 2 H2O 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Wilkinson's catalyst」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.